I don't believe there will ever be a tool that will do it right. Each website has different design qualities, that a program simply wouldn't recognize in our age. Adjustable screen resolution, matching of font & color, etc..
I suggest slicing that PSD up and getting Dreamweaver since you are already familiar with Adobe.
Try download the Dreamweaver trial, this program is the tool you are looking for
Any professional web designer will tell you that would they not trust a tool to code the entire template from a PSD.
Basically, designing the look of the page is an art, but so is coding it.
If you could learn Photoshop, you could learn basic HTML and CSS.
Good luck!
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