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I think it depends more on the audience of the site, for a site about books, one would think a weekday morning as 'bookies' are 1. Not usually at a book club, and 2. probably not reading as it is more of a night-time activity (for me at least.) If it was a site geared at the clubbing scene, I would think that late afternoon on Sunday would be the most impacting, as most people attend clubs on Friday/ Saturday night, after 7. To do this, I usually think of my target audience and what they will be doing and when, then try to fill in the downtime. From personal experience however, I have seen that it is not as important when the site is released, but the days following.
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