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It's possible to set up the right conditions to give this the best chance of happening, but it's not guaranteed. You need an additional page that is highly associated in content to the first, but is careful not to absolutely overlap on the keyword optimization. Then, push some links into that page both on and off site. Make sure there is more link building into the main page, so the second page remains secondary. It's a tricky balance and getting it right depends on your niche, but it's certainy possible to significantly increase your chances of this happening. Works best on large sites with lots of content - by that I means hundreds of pages of unique content. I've done this successfully on a number of sites/keywords.
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