Noooo, Oracle is more than capable of handling 10s of millions of records and can be superb to work with and develop apps for, Just the price is a little steep to say the least
But if you just want "playing" time to learn with, you can Download Oracle 10g and use the free Developer Licence.
MySQL might get a bit flakey with that number of rows but it's stablemate PostGre would be perfectly Ok. Both free under the right licensing use
MS SQL Server, shouldn't have any problems and the Access stuff should translate straight over. Licensing is pricey though.
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