most people like it in the center, if you notice any website you go to most of them have it center, but left is k too sometimes depending on the design.
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I don't know that it's automatically better, but I greatly prefer sites that are centered, at least those that have a fixed width to them.
I think by centering them it appears to leave less unused space around the site since the space is cut in half. To me it seems silly to have a site aligned to the left edge and then leave a lot of empty space on the right. I think the balance by centering the page is much better.
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Most of the center aligned sites I've seen still end up along the left edge on my PDA. If it's an issue you can create two style sheets one for a monitor and one for the mobile device.
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